Loch Lomond (North basin) Cailness NN 335062
Loch Lomond (South basin) Creinch NS 390890
Water, sediment and biota samples will be collected at the frequency shown and for the following determinands, as required by the UK programme, or included in addition to the required list because of environmental interest:
Determinand Frequency
Rivers
pH monthly
Suspended solids monthly
Temperature monthly
Conductivity monthly
Dissolved Oxygen monthly
Ammonium (as N) monthly
Total nitrogen monthly
Nitrate (as N) monthly
Nitrite (as N) monthly
Alkalinity monthly
Chloride monthly
Total organic carbon monthly
Particulate organic carbon monthly
Total phosphorus monthly
Phosphate (soluble reactive) monthly
Silicate monthly
Sulphate monthly
Sodium monthly
Potassium monthly
Calcium monthly
Magnesium monthly
Copper monthly
Zinc monthly
Cadmium monthly
Aluminium (total) monthly
Tin (total) monthly
Vanadium (total) monthly
Manganese (total) monthly
Iron (total) monthly
Mercury (total) daily
River flow
(Biota)
Invertebrates 3 x per year
Macrophytes 3 yearly
Epilithic diatoms annually
Fish annually
Additional CRPB Determinands
Waters Organochlorine pesticides monthly
PCBs monthly
Organo-Nitrogen pesticides monthly
Organo-Phosphorus pesticides monthly
Polyaromatic hydrocarbons (PAHs) monthly
Sediments Organochloride pesticides annually
Polyaromatic hydrocarbons (PAHs) annually
Cadmium, Chromium, Copper, Lead, annually
Nickel, Zinc annually
Biota Mosses - Cadmium, Chromium annually
Copper, Lead, Nickel, Zinc
Fish - Organochlorine pesticides annually
Loch Lomond
pH monthly
Secchi disk monthly
Temperature monthly
Conductivity monthly
Dissolved Oxygen monthly
Ammonium (as N) monthly
Total nitrogen monthly
Nitrate (as N) monthly
Nitrite (as N) monthly
Alkalinity monthly
Chloride monthly
Total organic carbon monthly
Particulate organic carbon monthly
Total phosphorus monthly
Phosphate (soluble reactive) monthly
Silicate monthly
Sulphate monthly
Sodium monthly
Potassium monthly
Calcium monthly
Magnesium monthly
Aluminium (total) monthly
Manganese (total) monthly
Iron (total) monthly
Mercury monthly
Chlorophyll-a monthly
Biota
Invertebrates annually
Epilithic diatoms 4 x year
Phytoplankton monthly
Zooplankton monthly
Macrophytes annually
Fish annually
Additional Determinands
Waters Organochlorine pesticides x 4 yearly
PCBs x 4 yearly
Organo-Nitrogen pesticides x 4 yearly
Organo-Phosphorus pesticides x 4 yearly
Polyaromatic hydrocarbons (PAHs) x 4 yearly
Sediments Organochlorine pesticides annually
Polyaromatic hydrocarbons (PAHs) annually
Cadmium, Chromium, Copper, Lead, annually
Nickel, Zinc, Arsenic, Redox
Biota Mosses - Cadmium, Chromium, annually
Copper, Lead, Nickel, Zinc
Fish
- Organochlorine pesticides annually
The
results that have been obtained to date from surveys of rivers and discharges
for the presence of a range of pesticidal substances (see Red List/Annex
1A survey) have shown that the great majority are at undetectable levels.
This is because many of the pesticidal substances in the Red List of substances
have been phase out of use, some many years ago.
However,
pesticides are used in agriculture to eliminate problems of insects, weeds
fungus and by local authorities and Railtrack to keep roads, paths and
railway lines free of weeds. Pesticides are also used in forestry operations
to protect trees from insect damage and to clear undergrowths of competing
weeds.
For
weedkilling, the preferred substances were the triazine compounds, particularly
simazine and atrazine. However, these pesticides have been withdrawn for
most uses because of problems with their persistence in drainage water
and receiving streams, and new compounds have been introduced as replacements.
Details
of the replacement substances were sought from the District and Regional
Councils and from Railtrack. They responded that the triazines have been
replaced by glyphosate and/or diuron. Both of these substances are readily
biodegradable, with diuron having a greater toxicity to freshwater fish
than glyphosate.
Although
the concentration of the triazine herbicides in urban rivers has declined
markedly in the last three years, monitoring of rivers for their presence,
and for diuron will continue over the weedkilling season (April- September).
For
the agricultural pesticides, information has been obtained from the Scottish
Agricultural Science Agency about the most commonly used pesticidal materials
used on farms in the former CRBs area. From the data supplied, the relative
toxicity to freshwater fish of the main substances used has been assessed.