lti_ecn_1.html

Further information: Environmental Change Network - Sampling Determinands
Abstract:

Two sites are being monitored on Loch Lomond in considerable detail for a wide range of chemical and biological parameters as part of a long-term UK programme to monitor environmental changes in rivers and lakes.

Loch Lomond (North basin) Cailness NN 335062

Loch Lomond (South basin) Creinch NS 390890

Water, sediment and biota samples will be collected at the frequency shown and for the following determinands, as required by the UK programme, or included in addition to the required list because of environmental interest:

Determinand Frequency

Rivers

pH monthly

Suspended solids monthly

Temperature monthly

Conductivity monthly

Dissolved Oxygen monthly

Ammonium (as N) monthly

Total nitrogen monthly

Nitrate (as N) monthly

Nitrite (as N) monthly

Alkalinity monthly

Chloride monthly

Total organic carbon monthly

Particulate organic carbon monthly

Total phosphorus monthly

Phosphate (soluble reactive) monthly

Silicate monthly

Sulphate monthly

Sodium monthly

Potassium monthly

Calcium monthly

Magnesium monthly

Copper monthly

Zinc monthly

Cadmium monthly

Aluminium (total) monthly

Tin (total) monthly

Vanadium (total) monthly

Manganese (total) monthly

Iron (total) monthly

Mercury (total) daily

River flow

(Biota)

Invertebrates 3 x per year

Macrophytes 3 yearly

Epilithic diatoms annually

Fish annually

Additional CRPB Determinands

Waters Organochlorine pesticides monthly

PCBs monthly

Organo-Nitrogen pesticides monthly

Organo-Phosphorus pesticides monthly

Polyaromatic hydrocarbons (PAHs) monthly

Sediments Organochloride pesticides annually

Polyaromatic hydrocarbons (PAHs) annually

Cadmium, Chromium, Copper, Lead, annually

Nickel, Zinc annually

Biota Mosses - Cadmium, Chromium annually

Copper, Lead, Nickel, Zinc

Fish - Organochlorine pesticides annually

Loch Lomond

pH monthly

Secchi disk monthly

Temperature monthly

Conductivity monthly

Dissolved Oxygen monthly

Ammonium (as N) monthly

Total nitrogen monthly

Nitrate (as N) monthly

Nitrite (as N) monthly

Alkalinity monthly

Chloride monthly

Total organic carbon monthly

Particulate organic carbon monthly

Total phosphorus monthly

Phosphate (soluble reactive) monthly

Silicate monthly

Sulphate monthly

Sodium monthly

Potassium monthly

Calcium monthly

Magnesium monthly

Aluminium (total) monthly

Manganese (total) monthly

Iron (total) monthly

Mercury monthly

Chlorophyll-a monthly

Biota

Invertebrates annually

Epilithic diatoms 4 x year

Phytoplankton monthly

Zooplankton monthly

Macrophytes annually

Fish annually

Additional Determinands

Waters Organochlorine pesticides x 4 yearly

PCBs x 4 yearly

Organo-Nitrogen pesticides x 4 yearly

Organo-Phosphorus pesticides x 4 yearly

Polyaromatic hydrocarbons (PAHs) x 4 yearly

Sediments Organochlorine pesticides annually

Polyaromatic hydrocarbons (PAHs) annually

Cadmium, Chromium, Copper, Lead, annually

Nickel, Zinc, Arsenic, Redox

Biota Mosses - Cadmium, Chromium, annually

Copper, Lead, Nickel, Zinc

Fish - Organochlorine pesticides annually
 

 
 




Environmental Change Network (Water Chemistry) - Pesticide Survey

The results that have been obtained to date from surveys of rivers and discharges for the presence of a range of pesticidal substances (see Red List/Annex 1A survey) have shown that the great majority are at undetectable levels. This is because many of the pesticidal substances in the Red List of substances have been phase out of use, some many years ago.
 

 

However, pesticides are used in agriculture to eliminate problems of insects, weeds fungus and by local authorities and Railtrack to keep roads, paths and railway lines free of weeds. Pesticides are also used in forestry operations to protect trees from insect damage and to clear undergrowths of competing weeds.
 

 

For weedkilling, the preferred substances were the triazine compounds, particularly simazine and atrazine. However, these pesticides have been withdrawn for most uses because of problems with their persistence in drainage water and receiving streams, and new compounds have been introduced as replacements.
 

 

Details of the replacement substances were sought from the District and Regional Councils and from Railtrack. They responded that the triazines have been replaced by glyphosate and/or diuron. Both of these substances are readily biodegradable, with diuron having a greater toxicity to freshwater fish than glyphosate.
 

 

Although the concentration of the triazine herbicides in urban rivers has declined markedly in the last three years, monitoring of rivers for their presence, and for diuron will continue over the weedkilling season (April- September).
 

 

For the agricultural pesticides, information has been obtained from the Scottish Agricultural Science Agency about the most commonly used pesticidal materials used on farms in the former CRBs area. From the data supplied, the relative toxicity to freshwater fish of the main substances used has been assessed.